Sitemap - IntelliMap by AveA
Putting a quick sitemap together helps tremendously as it gives you a high level view of what you're working with. It also helps you (and the client, stakeholder, etc.) picture how each screen will connect.
I tend to create these before any wireframes or UI design.
This was done in omnigraffle.
UPDATE:
Please disregard the duplicate "Add POI" screen that connects to "Customer List" in this photo. That was taken in an earlier iteration and has since been corrected :P
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